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A sample of octane in equilibrium with its vapor in a closed 1.0-L container has a vapor pressure of 50.0 torr at 45 °\degree C. The container's volume is increased to 2.0 L at constant temperature and the liquid/vapor equilibrium is reestablished. What is the vapor pressure?


A) > 50.0 torr
B) 50.0 torr
C) 25.0 torr
D) The mass of the octane vapor is needed to calculate the vapor pressure.
E) The external pressure is needed to calculate the vapor pressure.

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A metal with a body-centered cubic lattice will have ______ atom(s) per unit cell.


A) 1
B) 2
C) 3
D) 4
E) 9

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Of the five major types of crystalline solid, which would you expect each of the following to form? (e.g., H2O: molecular) A) Sn B) Si C) KCl D) Xe E) F2

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A) metallic
B) netw...

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In cubic closest packing, the unit cell is body-centered cubic.

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When liquid bromine is cooled to form a solid, which of the following types of solid would it form?


A) atomic
B) metallic
C) molecular
D) ionic
E) covalent network

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Which one of the following statements about unit cells and packing in solids is incorrect?


A) In any unit cell of a solid crystal, each face of the cell must have an opposite face which is equal and parallel to it.
B) The faces of a unit cell must all be at angles of 90 °\degree to each other.
C) The coordination number of atoms in a close packed metal is 12.
D) The packing efficiency in fcc structures is higher than in bcc structures.
E) The packing efficiency in fcc and hcp structures is the same.

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Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first?


A) Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first? A)    B)    C)    D)    E)  None of these choices is correct.
B) Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first? A)    B)    C)    D)    E)  None of these choices is correct.
C) Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first? A)    B)    C)    D)    E)  None of these choices is correct.
D) Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first? A)    B)    C)    D)    E)  None of these choices is correct.
E) None of these choices is correct.

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All gases can be liquefied at room temperature simply by increasing the pressure on the gas.

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The normal boiling point of ether is 307.8 K. Calculate the temperature at which its vapor pressure is exactly half of that at its normal boiling point. The heat of vaporization for ether is 26.69 kJ/mol.


A) 305 K
B) 302 K
C) 295 K
D) 289 K
E) 281 K

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Only molecules which do not have dipole moments can experience dispersion forces.

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The meniscus of mercury in a glass capillary tube is convex because of


A) the very high density of mercury as compared with water.
B) the low surface tension of mercury.
C) the greater attraction of mercury atoms to the glass than to each other.
D) the weaker attraction of mercury atoms to the glass than to each other.
E) electrostatic repulsion between the glass and the mercury.

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A temperature increase causes __________________ in the conductivity of a semiconductor.


A) a decrease
B) an increase
C) a modulation
D) an increase or decrease (depending on the semiconductor)
E) no change

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A temperature increase causes __________________ in the conductivity of a conductor.


A) a decrease
B) an increase
C) an increase or decrease (depending on the conductor)
D) a modulation
E) no change

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A liquid may be made to boil at room temperature, simply be lowering the pressure.

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Which of the following pairs is arranged with the particle of higher polarizability listed first?


A) Se2-, S2-
B) I, I-
C) Mg2+, Mg
D) Br, I
E) None of these choices is correct.

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The phase diagram of a substance shows the energy changes associated with changes of state.

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Ammonia's unusually high melting point is the result of


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) covalent bonding.
E) ionic bonding.

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