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Match the type of compound with the biological environment into which it is most likely to partition. -Weak acid


A) Bloodstream
B) Lipid membrane

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Given the pKa for ammonium ion is 9.26, what is the pH of 1 L of Solution which contains 5.35 g of NH4Cl, and contains the ammonium ion at a concentration of 0.2 mol L-1? (Molar mass of NH4Cl = 54.5 g mol-1.)


A) 7.00
B) 7.65
C) 8.96
D) 9.56
E) 9.95

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Which of the following depicts a neutralization reaction?


A) CH3CH2COOH ⇌ CH3CH2COO- + H+
B) CH3CH2COOH + NaOH CH3CH2COONa + H2O
C) CH3CH2COOH + CH3OH CH3CH2COOCH3 + H2O
D) CH3CH2COOH + H2O ⇌ CH3CH2COO- + H3O+

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Which of the following statements about buffer solutions are true? Select any that apply.


A) A buffer solution must contain a strong acid.
B) A buffer solution undergoes a neutralization reaction to consume excess OH- ions.
C) The conjugate acid present in the buffer solution consumes excess H+ ions.
D) The components of the buffer solution must be present at high concentrations.
E) A buffer solution can only resist changes in pH when small quantities of an acid or base are added to it.

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Match the following amino acids with the most appropriate description of the extent of ionization of their side chains when the pH of their environment has a value of 10.0 -Lysine (pKa 10.5)


A) Roughly 50% ionized
B) Less than 50% ionized
C) More than 50% ionized

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A

Look at the following equilibrium reaction: Look at the following equilibrium reaction:    Match each chemical species with the term that best describes its role in this reaction scheme. -Base A)  A B)  B C)  C D)  D Match each chemical species with the term that best describes its role in this reaction scheme. -Base


A) A
B) B
C) C
D) D

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Which of the following acids would you use to make an effective buffer for a reaction at pH 8?


A) Ethanoic acid; Ka = 1.7 10-5
B) Diphosphoric acid; Ka = 1.4 10-7
C) Tris-hydroxmethylaminoethane; Ka = 8.3 10-9
D) Ammonium chloride; Ka = 5.6 10-10
E) Sodium bicarbonate; Ka = 5.3 10-11

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Which one of the following is the correct expression for the ion product of water?


A) Which one of the following is the correct expression for the ion product of water? A)    B)    C)    D)    E)  log pH <font face= symbol ></font> log pOH
B) Which one of the following is the correct expression for the ion product of water? A)    B)    C)    D)    E)  log pH <font face= symbol ></font> log pOH
C) Which one of the following is the correct expression for the ion product of water? A)    B)    C)    D)    E)  log pH <font face= symbol ></font> log pOH
D) Which one of the following is the correct expression for the ion product of water? A)    B)    C)    D)    E)  log pH <font face= symbol ></font> log pOH
E) log pH log pOH

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A solution of HCl at concentration of 4 10-4 mol L-1 has a pH of which of the following?


A) 2.67
B) 3.21
C) 3.40
D) 4.31
E) 4.0

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The pH of human blood is 7.4. Therefore the hydrogen ion concentration in human blood is which of the following?


A) 7.4 M
B) 2.5 107 M
C) 1.6 103 M
D) 4.0 10-8 M
E) 7.4 10-7 M

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Which of the following is the weakest acid?


A) Boric acid, Ka = 7.3 10-10
B) Benzoic acid, Ka = 6.3 10-5
C) Sulfurous acid, Ka = 1.2 10-2
D) Ethanoic acid, Ka = 1.8 10-5
E) Formic acid, Ka = 1.8 10-4

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Look at the following equilibrium reaction: Look at the following equilibrium reaction:    Match each chemical species with the term that best describes its role in this reaction scheme. -Acid A)  A B)  B C)  C D)  D Match each chemical species with the term that best describes its role in this reaction scheme. -Acid


A) A
B) B
C) C
D) D

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If the concentration of [OH-] in an aqueous solution is 0.3 M, what is the pH of that solution?


A) 8.96
B) 10.87
C) 1.45
D) 3.67
E) 13.48

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Which of the following reactions depict the behaviour of an acid? Select any that apply.


A) NH3 + H+ ⇌ NH4+
B) CH3OOH- + ⇌CH3COOH
C) CH3COOH ⇌ CH3COO- + H+
D) H2O ⇌ H+ + OH-
E) H2O + H+ ⇌ H3O+

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A 0.1 M solution of ethanoic acid is 1.34% ionized. What is the value of Ka for ethanoic acid?


A) Ka = 5.3 10-11
B) Ka = 1.82 10-5
C) Ka = 1.34 10-6
D) Ka = 2.67 10-2
E) Ka = 3.01 10-4

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B

Match the type of compound with the biological environment into which it is most likely to partition. -Strong acid


A) Bloodstream
B) Lipid membrane

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Match the following amino acids with the most appropriate description of the extent of ionization of their side chains when the pH of their environment has a value of 10.0 -Arginine (pKa 12.5)


A) Roughly 50% ionized
B) Less than 50% ionized
C) More than 50% ionized

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The pH of a 0.005 M solution of hydrobromic acid is which of the following?


A) 1.3
B) 2.1
C) 2.3
D) 2.0
E) 5.0

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C

Match the following amino acids with the most appropriate description of the extent of ionization of their side chains when the pH of their environment has a value of 10.0 -Glutamic acid (pKa 4.1)


A) Roughly 50% ionized
B) Less than 50% ionized
C) More than 50% ionized

Correct Answer

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Look at the following equilibrium reaction: Look at the following equilibrium reaction:    Match each chemical species with the term that best describes its role in this reaction scheme. -Conjugate acid A)  A B)  B C)  C D)  D Match each chemical species with the term that best describes its role in this reaction scheme. -Conjugate acid


A) A
B) B
C) C
D) D

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