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When 1.50 g of Ba(s) is added to 100.00 g of water in a container open to the atmosphere,the reaction shown below occurs and the temperature of the resulting solution rises from 22.00°C to 33.10°C.If the specific heat of the solution is 4.18 J/(g ∙ °C) ,calculate ΔH for the reaction,as written. Ba(s) + 2 H2O(l) → Ba(OH) 2(aq) + H2(g) ΔH = ?


A) -431 kJ
B) -3.14 kJ
C) +3.14 kJ
D) +431 kJ

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The net reaction is represented by


A) arrow A.
B) arrow B.
C) arrow C.
D) line F.

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Which thermodynamic function is most related to disorder and probability?


A) enthalpy
B) internal energy
C) entropy
D) heat capacity

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  -What are the signs of ΔH and ΔS for the reaction represented in the above drawing? A) ΔH = +,ΔS = + B) ΔH = +,ΔS = - C) ΔH = -,ΔS = + D) ΔH = -,ΔS = - -What are the signs of ΔH and ΔS for the reaction represented in the above drawing?


A) ΔH = +,ΔS = +
B) ΔH = +,ΔS = -
C) ΔH = -,ΔS = +
D) ΔH = -,ΔS = -

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When the reaction below is performed in a water bath,will the temperature of the water bath increase or decrease? 432 kJ + A + 2 B → 3 C

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Kinetic energy increases with increasing ________ and increasing ________.

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The heat of vaporization of water at 100°C is 40.66 kJ/mol.Calculate the quantity of heat that is absorbed/released when 9.00 g of steam condenses to liquid water at 100°C.


A) 20.3 kJ of heat are absorbed.
B) 20.3 kJ of heat are released.
C) 81.3 kJ of heat are absorbed.
D) 81.3 kJ of heat are released.

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At 298 K the average kinetic energy is the same for H2,He,and N2.The gas with the highest average velocity is


A) H2.
B) He.
C) N2.
D) All have the same average velocity.

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Calculate the total quantity of heat required to convert 25.0 g of liquid CCl4(l) from 35.0°C to gaseous CCl4 76.8°C (the normal boiling point for CCl4) ? The specific heat of CCl4(l) is 0) 857 J/(g ∙°C) ,its heat of fusion is 3.27 kJ/mol,and its heat of vaporization is 29.82 kJ/mol.


A) 0) 896 kJ
B) 1) 43 kJ
C) 5) 74 kJ
D) 6) 28 kJ

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He gas is contained in a one-liter flask that is connected to an empty one-liter flask with a closed stopcock between the two flasks.When the stopcock is opened some of the He enters the evacuated flask.For this system


A) ΔH is negative and ΔS is positive
B) ΔH is zero and Δ△S is positive
C) ΔH is zero and ΔS is negative
D) ΔH is positive and ΔS is negative

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Methanol can be produced from carbon monoxide and hydrogen with suitable catalysts: CO(g) + 2 H2(g) → CH3OH(l) at 25°C ΔH° = -128.1 kJ and ΔS° = -332 J/K Find ΔG° at 25°C.


A) -157.2 kJ
B) -29.1 kJ
C) 98.9 kJ
D) 157.2 kJ

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The following drawing is a representation of a reaction for which ΔH° = +62 kJ.This reaction is likely to be The following drawing is a representation of a reaction for which ΔH° = +62 kJ.This reaction is likely to be   A) nonspontaneous at all temperatures. B) nonspontaneous at low temperatures and spontaneous at high temperatures. C) spontaneous at low temperatures and nonspontaneous at high temperatures. D) spontaneous at all temperatures.


A) nonspontaneous at all temperatures.
B) nonspontaneous at low temperatures and spontaneous at high temperatures.
C) spontaneous at low temperatures and nonspontaneous at high temperatures.
D) spontaneous at all temperatures.

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Water has an unusually high


A) electrical conductivity.
B) heat of combustion.
C) heat of formation.
D) specific heat.

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Which of the following is not a state function?


A) altitude
B) heat
C) internal energy
D) volume

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How much heat is absorbed/released when 20.00 g of NH3(g) reacts in the presence of excess O2(g) to produce NO(g) and H2O(l) according to the following chemical equation? 4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(l) ΔH° = +1168 kJ


A) 342.9 kJ of heat are absorbed.
B) 342.9 kJ of heat are released.
C) 1372 kJ of heat are absorbed.
D) 1372 kJ of heat are released.

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For the reaction 2CH4 (g) + 3 Cl2 (g) → 2 CHCl3 (l) + 3 H2 (g) ,ΔH° = -118.6 kJ. ΔH°f = -134.1 kJ/mol for CHCl3 (l) .Find ΔH°f for CH4 (g) .


A) -193.4 kJ/mol
B) -74.8 kJ/mol
C) 74.8 kJ/mol
D) 193.4 kJ/mol

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At constant pressure for the reaction shown below,what can be said about PΔV and ΔE? N2(g) + 3 H2(g) → 2 NH3(g) ΔH° = - 92.2 kJ


A) PΔV > 0 and ΔE > -92.2 kJ
B) PΔV > 0 and ΔE < -92.2 kJ
C) PΔV < 0 and ΔE > -92.2 kJ
D) PΔV < 0 and ΔE < -92.2 kJ

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Which is not a spontaneous process?


A) combustion of gasoline to produce carbon dioxide and water
B) diffusion of perfume in a room
C) dissolution of sodium chloride in water
D) freezing of water at 1°C

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Acetylene torches utilize the following reaction: 2 C2H2(g) + 5 O2(g) → 4 CO2(g) + 2 H2O(g) Use the given standard enthalpies of formation to calculate ΔH° for this reaction. Acetylene torches utilize the following reaction: 2 C<sub>2</sub>H<sub>2</sub>(g) + 5 O<sub>2</sub>(g) → 4 CO<sub>2</sub>(g) + 2 H<sub>2</sub>O(g)  Use the given standard enthalpies of formation to calculate ΔH° for this reaction.   A) 2512.4 kJ B) 1256.2 kJ C) -1256.2 kJ D) -2512.4 kJ


A) 2512.4 kJ
B) 1256.2 kJ
C) -1256.2 kJ
D) -2512.4 kJ

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For a process at constant pressure,


A) ΔE = w and q = 0.
B) ΔE = q and w = 0.
C) ΔE = ΔH.
D) ΔH = q.

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