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Kc is 1.67 × 1020 at 25 °C for the formation of iron(III) oxalate complex ion: Fe3+(aq) + 3C2O42-(aq) ⇌ [Fe(C2O4) 3]3-(aq) If 0.0200 mol L-1 Fe3+ is initially mixed with 1.00 mol L-1 oxalate ion,what is the concentration of Fe3+ ion at equilibrium?


A) 1.44 × 10-22 mol L-1
B) 0.0100 mol L-1
C) 8.35 × 1019 mol L-1
D) 6.94 × 1021 mol L-1

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Equilibrium reactions are noted by a single straight arrow for a yield sign.

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Which of the following equilibrium constants-reaction types is INCORRECT?


A) 1.4 × 1083 equilibrium reaction-goes to completion.
B) 1.6 × 10-23 equilibrium reaction-does not occur.
C) 1.8 × 10-5 equilibrium reaction-more reactants than products at equilibrium.
D) 1.0 equilibrium reaction-equal amounts of products and reactants.
E) 3.2 × 103 equilibrium reaction-more reactants than products at equilibrium.

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The equilibrium constant,Kp,equals 3.40 for the isomerization reaction: Cis-2-butene ⇌ trans-2-butene If a flask initially contains 0.250 bar of cis-2-butene and 0.165 bar of trans-2-butene,what is the equilibrium pressure of each gas?


A) P(cis-2-butene) = 0.0485 bar and P(trans-2-butene) = 0.165 bar
B) P(cis-2-butene) = 0.0458 bar and P(trans-2-butene) = 0.156 bar
C) P(cis-2-butene) = 0.0735 bar and P(trans-2-butene) = 0.250 bar
D) P(cis-2-butene) = 0.0943 bar and P(trans-2-butene) = 0.321 bar

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Consider the following reaction occurring at 960 K: CO2(g) + H2(g) ⇌ CO(g) + H2O(g) At equilibrium,the concentrations of reactants and products are: [CO2] = 0.0400 M,[H2] = 0.0220 M,[CO] = 0.0240 M,and [H2O] = 0.0190 M.This equilibrium is perturbed by adding CO2(g) to the system such that when a new equilibrium is reached,the concentration of CO2 is 0.050 M.What is the concentration of H2(g) at this equilibrium?


A) 0.050 M
B) 0.482 M
C) 0.462 M
D) 0.300 M
E) 0.0504 M

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For the reaction: 3 Fe(s) + 4 H2O(g) ⇌ Fe3O4(s) + 4 H2(g) Write the expression for Kp.


A) For the reaction: 3 Fe(s) + 4 H<sub>2</sub>O(g) ⇌ Fe<sub>3</sub>O<sub>4</sub>(s) + 4 H<sub>2</sub>(g)  Write the expression for Kp. A)    B)    C)    D)    E)
B) For the reaction: 3 Fe(s) + 4 H<sub>2</sub>O(g) ⇌ Fe<sub>3</sub>O<sub>4</sub>(s) + 4 H<sub>2</sub>(g)  Write the expression for Kp. A)    B)    C)    D)    E)
C) For the reaction: 3 Fe(s) + 4 H<sub>2</sub>O(g) ⇌ Fe<sub>3</sub>O<sub>4</sub>(s) + 4 H<sub>2</sub>(g)  Write the expression for Kp. A)    B)    C)    D)    E)
D) For the reaction: 3 Fe(s) + 4 H<sub>2</sub>O(g) ⇌ Fe<sub>3</sub>O<sub>4</sub>(s) + 4 H<sub>2</sub>(g)  Write the expression for Kp. A)    B)    C)    D)    E)
E) For the reaction: 3 Fe(s) + 4 H<sub>2</sub>O(g) ⇌ Fe<sub>3</sub>O<sub>4</sub>(s) + 4 H<sub>2</sub>(g)  Write the expression for Kp. A)    B)    C)    D)    E)

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Consider the reaction: 2 SO2(g) + O2(g) ⇌ 2 SO3(g) ,ΔrH° = -196.6 kJ/mol The equilibrium is displaced to the left if:


A) some sulfur trioxide is removed
B) the temperature is raised
C) some sulfur dioxide is added
D) the pressure is raised
E) the temperature is lowered

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Write the equilibrium constant expression for the reaction: 3 Sn(s) + 4 HNO3(aq) + H2O(l) ⇌ 3 H2SnO3(s) + 4 NO(g)


A) Kc = Write the equilibrium constant expression for the reaction: 3 Sn(s) + 4 HNO<sub>3</sub>(aq) + H<sub>2</sub>O(l) ⇌ 3 H<sub>2</sub>SnO<sub>3</sub>(s) + 4 NO(g)  A) K<sub>c</sub> =   B) K<sub>c</sub> =   C) K<sub>c</sub> =   D) K<sub>c</sub> =   E) K<sub>c</sub> =
B) Kc = Write the equilibrium constant expression for the reaction: 3 Sn(s) + 4 HNO<sub>3</sub>(aq) + H<sub>2</sub>O(l) ⇌ 3 H<sub>2</sub>SnO<sub>3</sub>(s) + 4 NO(g)  A) K<sub>c</sub> =   B) K<sub>c</sub> =   C) K<sub>c</sub> =   D) K<sub>c</sub> =   E) K<sub>c</sub> =
C) Kc = Write the equilibrium constant expression for the reaction: 3 Sn(s) + 4 HNO<sub>3</sub>(aq) + H<sub>2</sub>O(l) ⇌ 3 H<sub>2</sub>SnO<sub>3</sub>(s) + 4 NO(g)  A) K<sub>c</sub> =   B) K<sub>c</sub> =   C) K<sub>c</sub> =   D) K<sub>c</sub> =   E) K<sub>c</sub> =
D) Kc = Write the equilibrium constant expression for the reaction: 3 Sn(s) + 4 HNO<sub>3</sub>(aq) + H<sub>2</sub>O(l) ⇌ 3 H<sub>2</sub>SnO<sub>3</sub>(s) + 4 NO(g)  A) K<sub>c</sub> =   B) K<sub>c</sub> =   C) K<sub>c</sub> =   D) K<sub>c</sub> =   E) K<sub>c</sub> =
E) Kc = Write the equilibrium constant expression for the reaction: 3 Sn(s) + 4 HNO<sub>3</sub>(aq) + H<sub>2</sub>O(l) ⇌ 3 H<sub>2</sub>SnO<sub>3</sub>(s) + 4 NO(g)  A) K<sub>c</sub> =   B) K<sub>c</sub> =   C) K<sub>c</sub> =   D) K<sub>c</sub> =   E) K<sub>c</sub> =

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B

At a certain temperature the equilibrium constant,Kc,equals 0.11 for the reaction: 2 ICl(g) ⇌ I2(g) + Cl2(g) What is the equilibrium concentration of ICl if 0.45 mol of I2 and 0.45 mol of Cl2 are initially mixed in a 2.0 L flask?


A) 0.14 mol L-1
B) 0.17 mol L-1
C) 0.27 mol L-1
D) 0.34 mol L-1

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Consider the equilibrium system: N2O4(g) ⇌ 2 NO2(g) for which Kp = 0.1134 at 25 °C and ΔrH° = 58.03 kJ/mol.Assume that 1 mole of N2O4 and 2 moles of NO2 are introduced into a 5.0 liter container.What will be the equilibrium value of [N2O]?


A) 0.928 M
B) 0.0822 M
C) 0.358 M
D) 0.379 M
E) 0.042 M

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Consider the following reaction: POCl3(g) ⇌ POCl(g) + Cl2(g) with Kc = 0.450 A sample of pure POCl3(g) was placed in a reaction vessel and allowed to decompose according to the above reaction.At equilibrium,the concentrations of POCl(g) and Cl2(g) were each 0.150 M.What was the initial concentration of POCl3(g) ?


A) 0.225 M
B) 0.200 M
C) 0.633 M
D) 0.483 M
E) 0.350 M

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B

Consider the equilibrium system: N2O4(g) ⇌ 2 NO2(g) for which Kp = 0.1134 at 25 °C and ΔrH° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 1.00 atm at equilibrium and that initially only N2O4 was present inside the container,compute Consider the equilibrium system: N<sub>2</sub>O<sub>4</sub>(g) ⇌ 2 NO<sub>2</sub>(g) for which K<sub>p</sub> = 0.1134 at 25 °C and Δ<sub>r</sub>H° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 1.00 atm at equilibrium and that initially only N<sub>2</sub>O<sub>4</sub> was present inside the container,compute   At equilibrium. A) 0.398 atm B) 0.113 atm C) 0.602 atm D) 0.285 atm E) 0.715 atm At equilibrium.


A) 0.398 atm
B) 0.113 atm
C) 0.602 atm
D) 0.285 atm
E) 0.715 atm

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Consider the following hypothetical equilibrium reaction: A2(g) + B2(g) ⇌ 2 AB(g) where Kc = Consider the following hypothetical equilibrium reaction: A<sub>2</sub>(g) + B<sub>2</sub>(g) ⇌ 2 AB(g) <sup> </sup>where K<sub>c</sub> =   The equilibrium constant for the reaction: 2 A<sub>2</sub>(g) + 2 B<sub>2</sub>(g) ⇌ 4 AB(g) is ________. A)    B) K<sub>c</sub><sup>4 </sup> C)    <sub> </sub> D)    E) K<sub>c</sub><sup>2 </sup> The equilibrium constant for the reaction: 2 A2(g) + 2 B2(g) ⇌ 4 AB(g) is ________.


A) Consider the following hypothetical equilibrium reaction: A<sub>2</sub>(g) + B<sub>2</sub>(g) ⇌ 2 AB(g) <sup> </sup>where K<sub>c</sub> =   The equilibrium constant for the reaction: 2 A<sub>2</sub>(g) + 2 B<sub>2</sub>(g) ⇌ 4 AB(g) is ________. A)    B) K<sub>c</sub><sup>4 </sup> C)    <sub> </sub> D)    E) K<sub>c</sub><sup>2 </sup>
B) Kc4
C) Consider the following hypothetical equilibrium reaction: A<sub>2</sub>(g) + B<sub>2</sub>(g) ⇌ 2 AB(g) <sup> </sup>where K<sub>c</sub> =   The equilibrium constant for the reaction: 2 A<sub>2</sub>(g) + 2 B<sub>2</sub>(g) ⇌ 4 AB(g) is ________. A)    B) K<sub>c</sub><sup>4 </sup> C)    <sub> </sub> D)    E) K<sub>c</sub><sup>2 </sup>
D) Consider the following hypothetical equilibrium reaction: A<sub>2</sub>(g) + B<sub>2</sub>(g) ⇌ 2 AB(g) <sup> </sup>where K<sub>c</sub> =   The equilibrium constant for the reaction: 2 A<sub>2</sub>(g) + 2 B<sub>2</sub>(g) ⇌ 4 AB(g) is ________. A)    B) K<sub>c</sub><sup>4 </sup> C)    <sub> </sub> D)    E) K<sub>c</sub><sup>2 </sup>
E) Kc2

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E

In a system in equilibrium,two opposing reactions occur at equal rates.

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Consider the equilibrium system: N2O4(g) ⇌ 2 NO2(g) for which Kp = 0.1134 at 25 °C and ΔrH° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 10 atm at equilibrium and that initially only N2O4 was present inside the container,compute Consider the equilibrium system: N<sub>2</sub>O<sub>4</sub>(g) ⇌ 2 NO<sub>2</sub>(g) for which K<sub>p</sub> = 0.1134 at 25 °C and Δ<sub>r</sub>H° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 10 atm at equilibrium and that initially only N<sub>2</sub>O<sub>4</sub> was present inside the container,compute   At equilibrium.<sup> </sup> A) 7.98 atm B) 8.88 atm C) 1.12 atm D) 1.01 atm E) 8.99 atm At equilibrium.


A) 7.98 atm
B) 8.88 atm
C) 1.12 atm
D) 1.01 atm
E) 8.99 atm

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For the following chemical equilibrium,Kp = 4.6 × 10-14 at 25 °C,find the value of Kc for this reaction at 25 °C. 2 Cl2(g) + 2 H2O(g) ⇌ 4 HCl(g) + O2(g)


A) Kc = 1.9 × 10-15
B) Kc = 2.2 × 10-14
C) Kc = 1.1 × 10-12
D) Kc = 9.4 × 10-14
E) Kc = 4.6 × 10-14

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For the reaction CO(g) + 3 H2(g) ⇌ H2O(g) + CH4(g) ,Kc = 190 at 1000 K.If a vessel is filled with these gases such that the initial concentrations are [CO] = 0.025 M,[H2] = 0.045 M,[H2O] = 0.025,M and [CH4] = 0.046 M,in which direction will a reaction occur and why?


A) toward products because Qc = 0.17
B) toward reactants because Qc = 0.0029
C) toward products because Qc = 0.35
D) toward reactants because Qc = 505
E) it is at equilibrium because Qc = 1

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Choose the INCORRECT statement.


A) A certain amount of energy,called the activation energy,must be available if a reaction is to take place.
B) A reversible chemical reaction is one in which equilibrium is never established due to the constant decomposition of the products.
C) When the rate of the reverse reaction equals the rate of the forward reaction,equilibrium has been established.
D) Changes in temperature will change the value of an equilibrium constant.
E) Chemical equilibrium is a dynamic equilibrium.

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For the reaction CO(g) + 3 H2(g) ⇌ H2O(g) + CH4(g) ,Kc = 190 at 1000 K.If a vessel is filled with these gases such that the initial concentrations are [CO] = 0.036 M,[H2] = 0.045 M,[H2O] = 0.020,M and [CH4] = 0.031 M,in which direction will a reaction occur and why?


A) toward products because Qc = 0.38
B) toward reactants because Qc = 0.24
C) toward products because Qc = 4.1
D) toward reactants because Qc = 61
E) it is at equilibrium because Qc = 190

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Write the equilibrium constant expression for the following reaction: 2 KI(aq) + H2O2(aq) ⇌ 2 KOH(aq) + I2(aq)


A) Kc = Write the equilibrium constant expression for the following reaction: 2 KI(aq) + H<sub>2</sub>O<sub>2</sub>(aq) ⇌ 2 KOH(aq) + I<sub>2</sub>(aq)  A) K<sub>c</sub> =   B) K<sub>c</sub> = [I<sub>2</sub>] C) K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D) K<sub>c</sub> =   E) K<sub>c</sub> =
B) Kc = [I2]
C) Kc = [I2]2
D) Kc = Write the equilibrium constant expression for the following reaction: 2 KI(aq) + H<sub>2</sub>O<sub>2</sub>(aq) ⇌ 2 KOH(aq) + I<sub>2</sub>(aq)  A) K<sub>c</sub> =   B) K<sub>c</sub> = [I<sub>2</sub>] C) K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D) K<sub>c</sub> =   E) K<sub>c</sub> =
E) Kc = Write the equilibrium constant expression for the following reaction: 2 KI(aq) + H<sub>2</sub>O<sub>2</sub>(aq) ⇌ 2 KOH(aq) + I<sub>2</sub>(aq)  A) K<sub>c</sub> =   B) K<sub>c</sub> = [I<sub>2</sub>] C) K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D) K<sub>c</sub> =   E) K<sub>c</sub> =

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