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How is the reaction quotient used to determine whether a system is at equilibrium?


A) The reaction quotient must be satisfied for equilibrium to be achieved.
B) At equilibrium, the reaction quotient is undefined.
C) The reaction is at equilibrium when Q < Keq.
D) The reaction is at equilibrium when Q > Keq.
E) The reaction is at equilibrium when Q = Keq.

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The Keq for the equilibrium below is 0.112 at 700.0°C. SO2 (g) + The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)    2SO<sub>3</sub> (g)  A) 0.224 B) 0.335 C) 0.0125 D) 0.0560 E) 0.112 O2 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)    2SO<sub>3</sub> (g)  A) 0.224 B) 0.335 C) 0.0125 D) 0.0560 E) 0.112 SO3 (g) What is the value of Keq at this temperature for the following reaction? 2SO2 (g) + O2 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)    2SO<sub>3</sub> (g)  A) 0.224 B) 0.335 C) 0.0125 D) 0.0560 E) 0.112 2SO3 (g)


A) 0.224
B) 0.335
C) 0.0125
D) 0.0560
E) 0.112

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At equilibrium, __________.


A) all chemical reactions have ceased
B) the rates of the forward and reverse reactions are equal
C) the rate constants of the forward and reverse reactions are equal
D) the value of the equilibrium constant is 1
E) the limiting reagent has been consumed

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In what year was Fritz Haber awarded the Nobel Prize in chemistry for his development of a process for synthesizing ammonia directly from nitrogen and hydrogen?


A) 1954
B) 1933
C) 1918
D) 1900
E) 1912

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Pure __________ and pure __________ are excluded from equilibrium-constant expressions.

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Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO2 (g) + 2H2 (g) Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)    CH<sub>3</sub>OH (g)  A)    B)    C)    D)    E)   CH3OH (g)


A) Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)    CH<sub>3</sub>OH (g)  A)    B)    C)    D)    E)
B) Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)    CH<sub>3</sub>OH (g)  A)    B)    C)    D)    E)
C) Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)    CH<sub>3</sub>OH (g)  A)    B)    C)    D)    E)
D) Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)    CH<sub>3</sub>OH (g)  A)    B)    C)    D)    E)
E) Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)    CH<sub>3</sub>OH (g)  A)    B)    C)    D)    E)

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The equilibrium constant for the gas phase reaction N2 (g) + O2 (g) The equilibrium constant for the gas phase reaction N<sub>2</sub> (g) + O<sub>2</sub> (g)    2NO (g)  Is K<sub>eq</sub> = 4.20 × 10<sup>-31</sup> at 30°C. At equilibrium, __________. A) products predominate B) reactants predominate C) roughly equal amounts of products and reactants are present D) only products are present E) only reactants are present 2NO (g) Is Keq = 4.20 × 10-31 at 30°C. At equilibrium, __________.


A) products predominate
B) reactants predominate
C) roughly equal amounts of products and reactants are present
D) only products are present
E) only reactants are present

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Which of the following expressions is the correct equilibrium-constant expression for the reaction below? 2SO2 (g) + O2 (g) Which of the following expressions is the correct equilibrium-constant expression for the reaction below? 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)    2SO<sub>3</sub> (g)  A) [SO<sub>3</sub>] / [SO<sub>2</sub>][O<sub>2</sub>] B) [SO<sub>2</sub>] / [SO<sub>3</sub>] C) [SO<sub>3</sub>]<sup>2</sup> / [SO<sub>2</sub>]<sup>2</sup>[O<sub>2</sub>] D) [SO<sub>3</sub>]<sup>2</sup> / [SO<sub>2</sub>]<sup>2</sup>[O<sub>2</sub>]<sup>2</sup> E) [SO<sub>3</sub>] / [SO<sub>2</sub>][O<sub>2</sub>]<sup>2</sup> 2SO3 (g)


A) [SO3] / [SO2][O2]
B) [SO2] / [SO3]
C) [SO3]2 / [SO2]2[O2]
D) [SO3]2 / [SO2]2[O2]2
E) [SO3] / [SO2][O2]2

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The equilibrium constant for the gas phase reaction N2 (g) + 3H2 (g) The equilibrium constant for the gas phase reaction N<sub>2</sub><sub> </sub>(g) + 3H<sub>2</sub> (g)    2NH<sub>3</sub> (g)  Is K<sub>eq </sub>= 4.34 × 10<sup>-3</sup> at 300°C. At equilibrium, __________. A) products predominate B) reactants predominate C) roughly equal amounts of products and reactants are present D) only products are present E) only reactants are present 2NH3 (g) Is Keq = 4.34 × 10-3 at 300°C. At equilibrium, __________.


A) products predominate
B) reactants predominate
C) roughly equal amounts of products and reactants are present
D) only products are present
E) only reactants are present

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In the coal-gasification process, carbon monoxide is converted to carbon dioxide via the following reaction: CO (g) + H2O (g) In the coal-gasification process, carbon monoxide is converted to carbon dioxide via the following reaction: CO (g) + H<sub>2</sub>O (g)    CO<sub>2</sub> (g) + H<sub>2</sub> (g)  In an experiment, 0.35 mol of CO and 0.40 mol of H<sub>2</sub>O were placed in a 1.00-L reaction vessel. At equilibrium, there were 0.16 mol of CO remaining. K<sub>eq</sub> at the temperature of the experiment is __________. A) 5.5 B) 0.75 C) 0.93 D) 1.1 E) 1.0 CO2 (g) + H2 (g) In an experiment, 0.35 mol of CO and 0.40 mol of H2O were placed in a 1.00-L reaction vessel. At equilibrium, there were 0.16 mol of CO remaining. Keq at the temperature of the experiment is __________.


A) 5.5
B) 0.75
C) 0.93
D) 1.1
E) 1.0

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Consider the following reaction at equilibrium. 2CO2 (g) Consider the following reaction at equilibrium. 2CO<sub>2</sub> (g)    2CO (g) + O<sub>2</sub> (g) ΔH° = -514 kJ Le Châtelier's principle predicts that the equilibrium partial pressure of CO (g) can be maximized by carrying out the reaction __________. A) at high temperature and high pressure B) at high temperature and low pressure C) at low temperature and low pressure D) at low temperature and high pressure E) in the presence of solid carbon 2CO (g) + O2 (g) ΔH° = -514 kJ Le Châtelier's principle predicts that the equilibrium partial pressure of CO (g) can be maximized by carrying out the reaction __________.


A) at high temperature and high pressure
B) at high temperature and low pressure
C) at low temperature and low pressure
D) at low temperature and high pressure
E) in the presence of solid carbon

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Which one of the following will change the value of an equilibrium constant?


A) changing temperature
B) adding other substances that do not react with any of the species involved in the equilibrium
C) varying the initial concentrations of reactants
D) varying the initial concentrations of products
E) changing the volume of the reaction vessel

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Dinitrogentetraoxide partially decomposes according to the following equilibrium: N2O4 (g) Dinitrogentetraoxide partially decomposes according to the following equilibrium: N<sub>2</sub>O<sub>4</sub> (g)    2NO<sub>2</sub> (g)  A 1.00-L flask is charged with 0.0400 mol of N<sub>2</sub>O<sub>4</sub>. At equilibrium at 373 K, 0.0055 mol of N<sub>2</sub>O<sub>4</sub> remains. K<sub>eq</sub> for this reaction is __________. A) 2.2 × 10<sup>-4</sup> B) 13 C) 0.22 D) 0.022 E) 0.87 2NO2 (g) A 1.00-L flask is charged with 0.0400 mol of N2O4. At equilibrium at 373 K, 0.0055 mol of N2O4 remains. Keq for this reaction is __________.


A) 2.2 × 10-4
B) 13
C) 0.22
D) 0.022
E) 0.87

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At constant temperature, reducing the volume of a gaseous equilibrium mixture causes the reaction to shift in the direction that increases the number of moles of gas in the system.

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If the reaction quotient Q for a reaction is greater than the value of the equilibrium constant K for that reaction at a given temperature, __________ must be converted to __________ for the system to reach equilibrium.

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Consider the following chemical reaction: H2 (g) + I2 (g) Consider the following chemical reaction: H<sub>2</sub> (g) + I<sub>2</sub> (g)    2HI (g)  At equilibrium in a particular experiment, the concentrations of H<sub>2</sub>, I<sub>2</sub>, and HI were 0.25 M, 0.035 M, and 0.55 M, respectively. The value of K<sub>eq</sub> for this reaction is __________. A) 23 B) 63 C) 0.0090 D) 5.1 E) 34 2HI (g) At equilibrium in a particular experiment, the concentrations of H2, I2, and HI were 0.25 M, 0.035 M, and 0.55 M, respectively. The value of Keq for this reaction is __________.


A) 23
B) 63
C) 0.0090
D) 5.1
E) 34

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What role did Karl Bosch play in development of the Haber-Bosch process?


A) He discovered the reaction conditions necessary for formation of ammonia.
B) He originally isolated ammonia from camel dung and found a method for purifying it.
C) Haber was working in his lab with his instructor at the time he worked out the process.
D) He developed the equipment necessary for industrial production of ammonia.
E) He was the German industrialist who financed the research done by Haber.

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The equilibrium expression for Kp for the reaction below is __________. 2O3 (g) The equilibrium expression for K<sub>p</sub> for the reaction below is __________. 2O<sub>3 </sub>(g)    3O<sub>2 </sub>(g)  A)    B)    C)    D)    E)   3O2 (g)


A) The equilibrium expression for K<sub>p</sub> for the reaction below is __________. 2O<sub>3 </sub>(g)    3O<sub>2 </sub>(g)  A)    B)    C)    D)    E)
B) The equilibrium expression for K<sub>p</sub> for the reaction below is __________. 2O<sub>3 </sub>(g)    3O<sub>2 </sub>(g)  A)    B)    C)    D)    E)
C) The equilibrium expression for K<sub>p</sub> for the reaction below is __________. 2O<sub>3 </sub>(g)    3O<sub>2 </sub>(g)  A)    B)    C)    D)    E)
D) The equilibrium expression for K<sub>p</sub> for the reaction below is __________. 2O<sub>3 </sub>(g)    3O<sub>2 </sub>(g)  A)    B)    C)    D)    E)
E) The equilibrium expression for K<sub>p</sub> for the reaction below is __________. 2O<sub>3 </sub>(g)    3O<sub>2 </sub>(g)  A)    B)    C)    D)    E)

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Exactly 3.5 moles if N2O4 is placed in an empty 2.0-L container and allowed to reach equilibrium described by the equation N2O4 (g)⇌ 2NO2 (g) If at equilibrium the N2O4 is 25% dissociated, what is the value of the equilibrium constant for the reaction?

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The value of Keq for the equilibrium CO2 (g) + 2H2 (g) The value of K<sub>eq</sub> for the equilibrium CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)    CH<sub>3</sub>OH (g)  Is 14.5 at 483 °C. What is the value of K<sub>eq</sub> for the equilibrium below? 1/2 CO<sub>2</sub> + H<sub>2</sub> (g)    1/2 CH<sub>3</sub>OH (g)  A) 7.30 B) 7.35 C) 0.136 D) 3.81 E) 6.90 × 10<sup>-2</sup> CH3OH (g) Is 14.5 at 483 °C. What is the value of Keq for the equilibrium below? 1/2 CO2 + H2 (g) The value of K<sub>eq</sub> for the equilibrium CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)    CH<sub>3</sub>OH (g)  Is 14.5 at 483 °C. What is the value of K<sub>eq</sub> for the equilibrium below? 1/2 CO<sub>2</sub> + H<sub>2</sub> (g)    1/2 CH<sub>3</sub>OH (g)  A) 7.30 B) 7.35 C) 0.136 D) 3.81 E) 6.90 × 10<sup>-2</sup> 1/2 CH3OH (g)


A) 7.30
B) 7.35
C) 0.136
D) 3.81
E) 6.90 × 10-2

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