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Exam 8: Haloalkanes, Halogenation, and Radical Reactions

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Question 21

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The number of possible monobromination products of cyclopentane is______.

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Question 22

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Which of the following alkanes does not undergo monobromination to form a single bromoalkane as the major product?

A) 1
B) 2
C) 3
D) 4

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Question 23

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What type of reactive intermediate is formed upon irradiation of a solution of toluene (Ph-CH₃) and bromine?

Which halogen is most useful in the regioselective radical halogenation of alkenes??

What is the major organic product obtained from the following reaction?

What is the structure of all of the monobrominated products, including regioismers and stereoisomers, obtained from the following reaction?

What is the major product obtained from the reaction of 2-methyl-2-butene with hydrogen bromide in the presence of peroxides?

Provide the IUPAC name of the following compound (shown as a Fischer projection).

What is the major organic product obtained from the following reaction?

What is the reactive intermediate in the autooxidation of cyclohexene?

Provide the IUPAC name of the following compound (shown as a Fischer projection).

What is the major organic product obtained from the following reaction?

What is the major organic product obtained from the following reaction?

What is the IUPAC name of the following compound?

Consider the following reaction. In the absence of peroxides, the major product of the reaction is shown below.

During bromination using NBS, the concentration of bromine remains ________throughout the course of the reaction.

Which of the following statements is not true about the allyl radical

Which of the following has the list of compounds in the correct order of decreasing molecular polar (more polar > less polar) ?

The products of the addition of HBr to an alkene in the presence of peroxides is accounted for by a polar reaction mechanism.

What are the major organic products obtained from the following reaction?