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Consider the following reaction: 2H2O(g) + 2SO2(g) ⇌ 2H2S(g) + 3O2(g) A reaction mixture initially contains 2.8 mol L-1 H2O and 2.6 mol L-1 SO2.Determine the equilibrium concentration of H2S if Kc for the reaction at this temperature is 1.3 × 10-6 mol L-1.


A) 0.045 mol L-1
B) 0.058 mol L-1
C) 0.028 mol L-1
D) 3.1 × 10-3 mol L-1
E) 0.12 mol L-1

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Consider the following reaction at equilibrium.What effect will adding 1 mole of Ar to the reaction mixture have on the system? 2H2S(g) + 3O2(g) ⇌ 2H2O(g) + 2SO2(g)


A) The reaction will shift in the direction of products.
B) No effect will be observed.
C) The reaction will shift in the direction of reactants.
D) The equilibrium constant will decrease.
E) The equilibrium constant will increase.

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Consider the following reaction: Xe(g) + 2F2(g) ⇌ XeF4(g) A reaction mixture initially contains 2.24 bar Xe and 4.27 bar F2.If the equilibrium pressure of Xe is 0.34 bar,find the equilibrium constant (Kp) for the reaction.


A) 25 bar-2
B) 0.12 bar-2
C) 0.99 bar-2
D) 8.3 bar-2
E) 0.040 bar-2

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The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. \quad 2HD(g) ⇌ H2(g) + D2 \quad (g) K = 0.28 \quad 2H2(g) + 2D2(g) ⇌ 4HD \quad (g) K = ?


A) 7.8 × 10-2
B) 3.6
C) 0.53
D) 13
E) 1.9

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Consider the following reaction at equilibrium.What effect will increasing the pressure of the reaction mixture have on the system? 2H2S(g) + 3O2(g) ⇌ 2H2O(g) + 2SO2(g)


A) The reaction will shift in the direction of products.
B) No effect will be observed.
C) The reaction will shift in the direction of reactants.
D) The equilibrium constant will decrease.
E) The equilibrium constant will increase.

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How will equilibrium be affected for a reaction having the same number of moles of gaseous reactants and products if the pressure is increased?

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There will...

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Consider the following reaction at equilibrium.What effect will removing H2O have on the system? 2H2S(g) + 3O2(g) ⇌ 2H2O(g) + 2SO2(g)


A) The reaction will shift to the left.
B) No change will be observed.
C) The equilibrium constant will decrease.
D) The equilibrium constant will increase.
E) The reaction will shift in the direction of products.

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Express the equilibrium constant for the following reaction: P(g) + 3/2 Cl2(g) ? PCl3(g)


A) KP=P2(PCl3) P2(P) ×P3(Cl2) K P = \frac { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) }
B) KP=P1/2(PCl3) P1/2(P) ×P1/3(Cl2) K P = \frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^ { 1 / 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { Cl } _ { 2 } \right) }
C) KP=P(PCl3) P(P) ×P3/2(Cl2) K P = \frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
D) KP=P2(P) ×P3(Cl2) P2(PCl3) K P = \frac { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) }
E) Kp=P(P) ×P3/2(Cl2) P(PCl3) K p = \frac { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2} \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) }

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Consider the following reaction: CO2(g) + C(graphite) ⇌ 2CO(g) A reaction mixture initially contains 0.56 bar CO2 and 0.32 bar CO.Determine the equilibrium pressure of CO if Kp for the reaction at this temperature is 2.25 bar.


A) 0.83 bar
B) 0.31 bar
C) 0.26 bar
D) 0.58 bar
E) 0.42 bar

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Express the equilibrium constant for the following reaction: N2(g) + 3H2(g) ? 2NH3(g)


A) KP = P(N2) ×P1/3(H2) P1/2(NH3) \frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P }^{ 1 / 3 }\left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^{1 / 2 }\left( \mathrm { NH } _ { 3 } \right) }
B) KP = P6(NH3) P3( N2) ×P9(H2) \frac { \mathrm { P } ^ { 6 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } ^ { 3 } \left( \mathrm {~N} _ { 2 } \right) \times \mathrm { P } ^ { 9 } \left( \mathrm { H } _ { 2 } \right) }
C) KP = P2(NH3) P(N2) ×P3(H2) \frac { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) }
D) KP= P(N2) ×P3(H2) P2(NH3) \frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) }
E) KP = P1/2(NH3) P(N2) ×P1/3(H2) \frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { H } _ { 2 } \right) }

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Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(NOCl) eq = 0.22 atm,P(NO) eq = 0.10 atm,P(Cl2) eq = 0.081 atm. \quad\quad 2NOCl(g) ⇌ 2NO(g) + Cl2(g)


A) 3.7 × 10-2 atm
B) 60 atm
C) 27 atm
D) 1.7 × 10-2 atm
E) 1.8 × 10-3 atm

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Express the equilibrium constant for the following reaction: Fe(H2O) 63+3+(aq) +6CN(aq) =Fe(CN) 633(aq) +6H2O(l) \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \underset { ( a q ) } { 3 + } + 6 \mathrm { CN } - ( a q ) = \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \underset { ( a q ) } { 3 - } + 6 \mathrm { H } _ { 2 } \mathrm { O } ( l )


A) Kc = [Fe(CN) 63][CN]6×[Fe(H2O) 63+]\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] }
B) Kc = [Fe(CN) 63]×[H2O]6[CN]6×[Fe(H2O) 63+]\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 6 } } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \right] }
C) Kc = [CN]6×[Fe(H2O) 63+][Fe(CN) 63]\frac { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] } { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] }
D) Kc = [CN]6×[Fe(H2O) 63+][Fe(CN) 63]×[H2O]6\frac { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] } { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 6 } }
E) Kc = [Fe(CN) 63]3[CN]6×[Fe(H2O) 63+]3\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] ^ { 3 } } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \right] ^ { 3 } }

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The reaction below has a Kc value of 1.0 × 1012 M-1.What is the value of Kp for this reaction at 500 K? \quad 2SO2(g) + O2(g) ⇌ 2SO3(g)


A) 4.2 × 10-11 bar-1
B) 1.0 × 1012 bar-1
C) 2.4 × 10-12 bar-1
D) 4.1 × 1013 bar-1
E) 2.4 × 1010 bar-1

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An equilibrium mixture of CO,O2,and CO2 at a certain temperature contains 0.0010 mol L-1 CO2 and 0.0015 mol L-1 O2.At this temperature,Kc equals 1.4 × 102 L mol-1 for the reaction: 2CO(g) + O2(g) ⇌ 2CO2(g) What is the equilibrium concentration of CO?


A) 4.8 × 10-6 mol L-1
B) 8.5 × 10-3 mol L-1
C) 9.3 × 10-2 mol L-1
D) 3.1 × 10-1 mol L-1

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At a certain temperature the equilibrium constant,Kc,equals 0.11 for the reaction: \quad\quad\quad 2ICl(g) ⇌ I2(g) + Cl2(g) What is the equilibrium concentration of ICl if 0.75 mol of I2 and 0.75 mol of Cl2 are initially mixed in a 2.0 L flask?


A) 0.23 mol L-1
B) 0.28 mol L-1
C) 0.225 mol L-1
D) 0.56 mol L-1

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Consider the following reaction at equilibrium.What effect will reducing the volume of the reaction mixture have on the system? Xe(g) + 2F2(g) ⇌ XeF4(g)


A) The reaction will shift to the left in the direction of reactants.
B) The equilibrium constant will increase.
C) No effect will be observed.
D) The reaction will shift to the right in the direction of products.
E) The equilibrium constant will decrease.

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For the following reaction,what is Δn required in the conversion of Kc to Kp? \quad\quad N2(g) + 3H2(g) ⇌ 2NH3(g)


A) 4
B) -4
C) -2
D) 2
E) 1

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The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant. \quad A(g) + 2B(g) ⇌ AB2 \quad (g) Kc = 59 \quad AB2(g) + B(g) ⇌ AB3 \quad (g) Kc = ? \quad A(g) + 3B(g) ⇌ AB3 \quad (g) Kc = 478


A) 3.5 × 10-5
B) 2.8 × 104
C) 8.1
D) 0.12
E) 89

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 1.5 mol L-1,[H2]eq = 1.1 mol L-1,[NH3]eq = 0.47 mol L-1. \quad\quad N2(g) + 3H2(g) ⇌ 2NH3(g)


A) 3.5 M-2
B) 0.28 M-2
C) 9.1 M-2
D) 0.11 M-2
E) 0.78 M-2

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Can the Kp and Kc for a reaction ever have the same value? Why or why not?

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Yes,they can have the same value.Since K...

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