Question 1

Complete the following reaction sequence,giving structural details of all key intermediates.
Bromocyclohexane $\to$
i)Li
ii)CuI
iii)4-methyl-1-bromohexane

Accepted Answer

The answer of Complete the following reaction sequence,giving structural details...

Question 2

What is the product,A,that would be obtained from the following reaction sequence?

Accepted Answer

A)  I
B)  II
C)  III
D)  IV
E)  V

Question 3

Reaction of excess methyllithium with ethyl acetate (CH3CO2C2H5)produces,after acid work-up,___.

Accepted Answer

t-butyl al...

Question 4

What would be the product,A,of the following reaction sequence? 3CH2CH2CH3 B)    C)    D) CH3CH2CH2CH2OD E) CH3CH2CH2CH2D" class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  CH3CH2CH2CH3
B)   3CH2CH2CH3 
B)     
C)     
D)  CH3CH2CH2CH2OD 
E)  CH3CH2CH2CH2D" class="answers-bank-image d-inline" rel="preload" >
C)   3CH2CH2CH3 
B)     
C)     
D)  CH3CH2CH2CH2OD 
E)  CH3CH2CH2CH2D" class="answers-bank-image d-inline" rel="preload" >
D)  CH3CH2CH2CH2OD
E)  CH3CH2CH2CH2D

Question 5

Which of the reagents listed below would efficiently accomplish the transformation of 2-methyl-3-cyclopentenol into 2-methyl-3-cyclopentenone? 4(aq,alkaline)  B) CrO3/H2SO4 C) H2,Pt D) Br2,CCl4 E) Two of these choices." class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  KMnO4(aq,alkaline) 
B)  CrO3/H2SO4
C)  H2,Pt
D)  Br2,CCl4
E)  Two of these choices.

Question 6

Which product is formed from the following transformation:

Accepted Answer

A)  
B)  
C)  
D)  
E)  None of these choices.

Question 7

Key to the usefulness of PCC/CH2Cl2 as a selective oxidant for the production of aldehydes from 1S1U1P1$\circ$S1S1P0 alcohols is ___.

Accepted Answer

the inability to for...

Question 8

Predict the product(s) of the following reaction sequence:

Accepted Answer

A)  A mixture of I and II
B)  A mixture of I and III
C)  A mixture of II and III
D)  A mixture of II and IV
E)  A mixture of III and IV

Question 9

A solution of CrO3 or Na2Cr2O7 in aqueous sulfuric acid is called the ___.

Accepted Answer

Question 10

Which of the reagents listed below would serve as the basis for a simple chemical test to distinguish between (CH3) 3COH and (CH3) 2CHCH2OH?

Accepted Answer

A)  NaH
B)  NaOH/H2O
C)  Br2 in CCl4
D)  Cold conc.H2SO4
E)  Jones reagent

Question 11

Which of these compounds cannot be reduced by sodium borohydride?

Accepted Answer

A)   
B)   
C)   
D)   
E)  Two of these choices cannot be reduced.

Question 12

What is the product,A,that would be obtained from the following reaction sequence?

Accepted Answer

A)  I
B)  II
C)  III
D)  IV
E)  V

Question 13

Predict the product(s)of the following reaction sequence:

Accepted Answer

The answer of Predict the product(s)of the following reaction sequence:...

Question 14

Consider the molecule 2SO4 B) Br2/CCl4 C) NaOH(aq)  D) CrO3/H2SO4 E) Dilute KMnO4/H2O" class="answers-bank-image d-inline" rel="preload" > Which reagent will not give a positive test with this compound?

Accepted Answer

A)  Cold conc.H2SO4
B)  Br2/CCl4
C)  NaOH(aq) 
D)  CrO3/H2SO4
E)  Dilute KMnO4/H2O

Question 15

Suggest a reasonable synthetic strategy for the synthesis of 4-methyl-1,4-pentanediol from 4-hydroxybutanone HOCH2CH2CH2COCH3.

Accepted Answer

Question 16

The final product,E,in the following reaction sequence is,

Accepted Answer

A)  I
B)  II
C)  III
D)  IV
E)  V

Question 17

What would be the final product,D,in the following reaction sequence?

Accepted Answer

A)  I
B)  II
C)  III
D)  IV
E)  V

Question 18

Predict the product(s) of the following reaction:

Accepted Answer

A)  A mixture of I and II
B)  A mixture of I and III
C)  A mixture of II and III
D)  A mixture of II and IV
E)  A mixture of III and IV

Question 19

Which of the reagents/techniques listed below would serve as the basis for a simple chemical test to distinguish between CH3CH2CH=CHCH2CH2CHO and CH3CH2CH=CHCH2CH2CH2OH?

Accepted Answer

A)  KMnO4
B)  IR spectroscopy
C)  Br2 in CCl4
D)  Two of these choices.
E)  All of these choices.

Question 20

What would be the product,A,of the following reaction sequence? 3CH2CH2CH3 B)    C)    D) CH3CH2CH2CH2OD E) CH3CH2CH2CH2D" class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  CH3CH2CH2CH3
B)   3CH2CH2CH3 
B)     
C)     
D)  CH3CH2CH2CH2OD 
E)  CH3CH2CH2CH2D" class="answers-bank-image d-inline" rel="preload" >
C)   3CH2CH2CH3 
B)     
C)     
D)  CH3CH2CH2CH2OD 
E)  CH3CH2CH2CH2D" class="answers-bank-image d-inline" rel="preload" >
D)  CH3CH2CH2CH2OD
E)  CH3CH2CH2CH2D

Exam 12: Alcohols From Carbonyl Compounds

Key to the usefulness of PCC/CH2Cl2 as a selective oxidant for the production of aldehydes from 1 ∘\circ∘ alcohols is ___.

Correct Answerverifiedthe inability to for...View AnswerShow Answer

What would be the product,A,of the following reaction sequence?

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What would be the product,A,of the following reaction sequence?

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Which of the reagents listed below would efficiently accomplish the transformation of 2-methyl-3-cyclopentenol into 2-methyl-3-cyclopentenone?

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Which of the reagents listed below would serve as the basis for a simple chemical test to distinguish between (CH3) 3COH and (CH3) 2CHCH2OH?

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Which product is formed from the following transformation:

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Which of the reagents/techniques listed below would serve as the basis for a simple chemical test to distinguish between CH3CH2CH=CHCH2CH2CHO and CH3CH2CH=CHCH2CH2CH2OH?

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Suggest a reasonable synthetic strategy for the synthesis of 4-methyl-1,4-pentanediol from 4-hydroxybutanone HOCH2CH2CH2COCH3.

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Predict the product(s) of the following reaction sequence:

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Which of these compounds cannot be reduced by sodium borohydride?

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What is the product,A,that would be obtained from the following reaction sequence?

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What is the product,A,that would be obtained from the following reaction sequence?

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What would be the final product,D,in the following reaction sequence?

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Complete the following reaction sequence,giving structural details of all key intermediates. Bromocyclohexane →\to→ i)Li ii)CuI iii)4-methyl-1-bromohexane

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Predict the product(s)of the following reaction sequence:

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The final product,E,in the following reaction sequence is,

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Predict the product(s) of the following reaction:

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Consider the molecule Which reagent will not give a positive test with this compound?

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Reaction of excess methyllithium with ethyl acetate (CH3CO2C2H5)produces,after acid work-up,___.

Correct Answerverifiedt-butyl al...View AnswerShow Answer

A solution of CrO3 or Na2Cr2O7 in aqueous sulfuric acid is called the ___.

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Key to the usefulness of PCC/CH₂Cl₂ as a selective oxidant for the production of aldehydes from 1^$\circ$ alcohols is ___.

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the inability to for...
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Which of the reagents listed below would serve as the basis for a simple chemical test to distinguish between (CH₃) ₃COH and (CH₃) ₂CHCH₂OH?

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Which of the reagents/techniques listed below would serve as the basis for a simple chemical test to distinguish between CH₃CH₂CH=CHCH₂CH₂CHO and CH₃CH₂CH=CHCH₂CH₂CH₂OH?

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Suggest a reasonable synthetic strategy for the synthesis of 4-methyl-1,4-pentanediol from 4-hydroxybutanone HOCH₂CH₂CH₂COCH₃.

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Complete the following reaction sequence,giving structural details of all key intermediates. Bromocyclohexane $\to$ i)Li ii)CuI iii)4-methyl-1-bromohexane

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Reaction of excess methyllithium with ethyl acetate (CH₃CO₂C₂H₅)produces,after acid work-up,___.

Correct Answer
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t-butyl al...
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A solution of CrO₃ or Na₂Cr₂O₇ in aqueous sulfuric acid is called the ___.

Correct Answer
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